• Source: Zinc nitrate

Zinc nitrate is an inorganic chemical compound with the formula Zn(NO3)2. This colorless, crystalline salt is highly deliquescent. It is typically encountered as a hexahydrate Zn(NO3)2·6H2O. It is soluble in both water and alcohol.




Synthesis


Zinc nitrate is usually prepared by dissolving zinc metal, zinc oxide, or related materials in nitric acid:

Zn + 2 HNO3 → Zn(NO3)2 + H2
ZnO + 2 HNO3 → Zn(NO3)2 + H2O
These reactions are accompanied by the hydration of the zinc nitrate.
The anhydrous salt arises by the reaction of anhydrous zinc chloride with nitrogen dioxide:

ZnCl2 + 4 NO2 → Zn(NO3)2 + 2 NOCl




Reactions


Treatment of zinc nitrate with acetic anhydride gives zinc acetate.
On heating, zinc nitrate undergoes thermal decomposition to form zinc oxide, nitrogen dioxide and oxygen:

2 Zn(NO3)2 → 2 ZnO + 4 NO2 + 1 O2
Aqueous zinc nitrate contains aquo complexes [Zn(H2O)6]2+ and [Zn(H2O)4]2+. and, thus, this reaction may be better written as the reaction of the aquated ion with hydroxide through donation of a proton, as follows.




Applications


Zinc nitrate has no large scale application but is used on a laboratory scale for the synthesis of coordination polymers. Its controlled decomposition to zinc oxide has also been used for the generation of various ZnO based structures, including nanowires.
It can be used as a mordant in dyeing. An example reaction gives a precipitate of zinc carbonate:

Zn(NO3)2 + Na2CO3 → ZnCO3 + 2 NaNO3




References

Kata Kunci Pencarian:

• Media Murashige dan Skoog
• Pupuk
• Bilangan oksidasi
• Pentazola
• Kamus rumus kimia
• Zinc nitrate
• Zinc oxide
• Zinc acetate
• Cadmium nitrate
• Zinc
• List of inorganic compounds
• Cerium nitrates
• Nitrate test
• Mercury(II) nitrate
• Lead(II) nitrate