- Source: Bromopentaamminecobalt(III) bromide
Bromopentaamminecobalt(III) bromide is the dibromide salt of the cobalt coordination compound with the formula [Co(NH3)5Br]2+. It is a purple, water-soluble solid. The analogous chloropentaamminecobalt(III) chloride is also well known.
Synthesis and reactions
The title compound is prepared by oxidation of a solution of cobalt(II) salts in aqueous ammonia.
2 CoBr2 + 8 NH3 + 2 NH4Br + H2O2 → 2 [Co(NH3)5Br]Br2 + 2 H2O
It was first reported in the 1870s, before the structure or even formulae were understood for such complexes. This early work showed that only two thirds of the bromide groups were exchangeable with other anions such as nitrate and dithionate.
The complex undergoes aquation, meaning that bromide is displaced by water:
[Co(NH3)5Br]Br2 + H2O → [Co(NH3)5(H2O)]Br3
This process is catalyzed by platinum.
References
Further reading
Loehlin, James H. "The Study of a Cobalt Complex-A Laboratory Project." Journal of Chemical Education. doi:10.1021/ed059p1048
Williams, Gregory M; Olmsted, John, III; Preksa, Andrew P., III (1989). "Coordination complexes of cobalt: inorganic synthesis in the general chemistry laboratory". Journal of Chemical Education. 66 (12): 1043–5. Bibcode:1989JChEd..66.1043W. doi:10.1021/ed066p1043.{{cite journal}}: CS1 maint: multiple names: authors list (link)
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