- Source: Chloric acid
Chloric acid, HClO3, is an oxoacid of chlorine, and the formal precursor of chlorate salts. It is a strong acid (pKa ≈ −2.7) and an oxidizing agent.
Properties
Chloric acid is thermodynamically unstable with respect to disproportionation.
Chloric acid is stable in cold aqueous solution up to a concentration of approximately 30%, and solution of up to 40% can be prepared by careful evaporation under reduced pressure. Above these concentrations, chloric acid solutions decompose to give a variety of products, for example:
8 HClO3 → 4 HClO4 + 2 H2O + 2 Cl2 + 3 O2
3 HClO3 → HClO4 + H2O + 2 ClO2
Hazards
Chloric acid is a powerful oxidizing agent. Most organics and flammables will deflagrate on contact.
Production
It can be prepared by the reaction of sulfuric acid with barium chlorate, the insoluble barium sulfate being removed by precipitation:
Ba(ClO3)2 + H2SO4 → 2 HClO3 + BaSO4
Another method is the heating of hypochlorous acid, producing chloric acid and hydrogen chloride:
3 HClO → HClO3 + 2 HCl
See also
Chlorate
Hypochlorous acid
Chlorous acid
Perchloric acid
Oxidizing acid
Dichlorine pentoxide
References
Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
R. Bruce King, ed. (1994). "Chloric acid". Encyclopedia of Inorganic Chemistry. Vol. 2. Chichester: Wiley. p. 658. ISBN 0-471-93620-0.
Kata Kunci Pencarian:
- Asam klorat
- Asam perklorat
- Kalium heksakloroplatinat
- Asam kloroplatinat
- Diklorin heptoksida
- Klorin
- Platina
- Metaloid
- Kamus rumus kimia
- Pencirian nanopartikel
- Chloric acid
- Barium chlorate
- Perchloric acid
- Iodic acid
- Oxidizing acid
- Chlorous acid
- Potassium chlorate
- Chlorine acid
- Acid strength
- Oxyacid
