- Source: Molybdenum oxytetrafluoride
Molybdenum oxytetrafluoride is the inorganic compound with the formula MoOF4. It is a white, diamagnetic solid. According to X-ray crystallography, it is a coordination polymer consisting of a linear chain of alternating Mo and F atoms. Each Mo center is octahedral, the coordination sphere being defined by oxide, three terminal fluorides, and two bridging fluorides. In contrast to this motif, tungsten oxytetrafluoride crystallizes as a tetramer, again with bridging fluoride ligands.
Reactions
The acetonitrile adduct of molybdenum oxytetrafluoride can be prepared by treating molybdenum hexafluoride with hexamethyldisiloxane in acetonitrile:
MoF6 + [(CH3)3Si]2O + CH3CN → MoOF4(NCCH3) + 2 (CH3)3SiF
Molybdenum oxytetrafluoride is susceptible to hydrolysis to give molybdenum difluoride dioxide.
References
Kata Kunci Pencarian:
- Kamus rumus kimia
- Molybdenum oxytetrafluoride
- Molybdenum oxyfluoride
- Tungsten oxytetrafluoride
- Molybdenum difluoride dioxide
- Tungsten oxyfluoride
- List of CAS numbers by chemical compound
- Chromyl fluoride
- Glossary of chemical formulae
- Tungsten(VI) oxytetrachloride
- Molecular symmetry
