• Source: Neptunium(IV) phosphide
    • Neptunium(IV) phosphide is a binary inorganic compound of neptunium metal and phosphorus with the chemical formula Np3P4.


      Preparation


      Neptunium(IV) phosphide can be formed from the fusion of stoichiometric amounts of neptunium and red phosphorus in an evacuated and sealed quartz tube at 750 °C:

      3Np + 4P → Np3P4


      Physical properties


      Neptunium(IV) phosphide forms black crystals of cubic crystal system, spatial group I 43d. Isostructural with Th3P4.
      It does not dissolve in water.


      Chemical properties


      The compound reacts with concentrated HCl to give a green solution:

      Np3P4 + 12HCl → 3NpCl4 + 4PH3


      References

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