- Source: Silver sulfate
Silver sulfate is the inorganic compound with the formula Ag2SO4. It is a white solid with low solubility in water.
Preparation and structure
Silver sulfate precipitates as a solid when an aqueous solution of silver nitrate is treated with sulfuric acid:
2 AgNO3 + H2SO4 → Ag2SO4 + 2 HNO3
It is purified by recrystallization from concentrated sulfuric acid, a step that expels traces of nitrate.
Silver sulfate and anhydrous sodium sulfate adopt the same structure.
Silver(II) sulfate
The synthesis of silver(II) sulfate (AgSO4) with a divalent silver ion instead of a monovalent silver ion was first reported in 2010 by adding sulfuric acid to silver(II) fluoride (HF escapes). It is a black solid that decomposes exothermically at 120 °C with evolution of oxygen and the formation of the pyrosulfate.
AgF2 + H2SO4 → AgSO4 + 2 HF
4 AgSO4 → 2 Ag2S2O7 + O2
References
Kata Kunci Pencarian:
- Besi(III) sulfat
- Kalium
- Nikel
- Logam alkali
- Tembaga
- Belerang
- Seng
- Magnesium
- Emas
- Vanadium
- Silver sulfate
- Copper(II) sulfate
- Barium sulfate
- Sulfate
- Silver sulfite
- Silver chloride
- Iron(II) sulfate
- Mercury(I) sulfate
- Iron(III) sulfate
- List of inorganic compounds