• Source: Tetraethyl orthosilicate

Tetraethyl orthosilicate, formally named tetraethoxysilane (TEOS), ethyl silicate is the organic chemical compound with the formula Si(OC2H5)4. TEOS is a colorless liquid. It degrades in water. TEOS is the ethyl ester of orthosilicic acid, Si(OH)4. It is the most prevalent alkoxide of silicon.
TEOS is a tetrahedral molecule. Like its many analogues, it is prepared by alcoholysis of silicon tetrachloride:

SiCl4 + 4 EtOH → Si(OEt)4 + 4 HCl
where Et is the ethyl group, C2H5, and thus EtOH is ethanol.




Applications


TEOS is mainly used as a crosslinking agent in silicone polymers and as a precursor to silicon dioxide in the semiconductor industry.
TEOS is also used as the silica source for synthesis of some zeolites. Other applications include coatings for carpets and other objects. TEOS is used in the production of aerogel. These applications exploit the reactivity of the Si-OR bonds. TEOS has historically been used as an additive to alcohol based rocket fuels to decrease the heat flux to the chamber wall of regeneratively cooled engines by over 50%.
TEOS is used in steel casting industry as an inorganic binder and stiffener for making silica-based ceramic molding forms (see also sodium silicate).
As inorganic binder for coatings (passivation) of different materials such as steel, glass, brass, and even wood in order to make surfaces water-, oxygen- and high-temperature resistant.
As additive to solid polymers to enhance adhesiveness to glass, steel or wood.
As a binder for porcelain teeth crowns.
As precursor to siloxanes.




Other reactions


TEOS easily converts to silicon dioxide upon the addition of water:

Si(OC2H5)4 + 2 H2O → SiO2 + 4 C2H5OH
An idealized equation is shown, in reality the silica produced is hydrated. This hydrolysis reaction is an example of a sol-gel process. The side product is ethanol. The reaction proceeds via a series of condensation reactions that convert the TEOS molecule into a mineral-like solid via the formation of Si-O-Si linkages. Rates of this conversion are sensitive to the presence of acids and bases, both of which serve as catalysts. The Stöber process allows the formation of monodisperse and mesoporous silica.
At elevated temperatures (>600 °C), TEOS converts to silicon dioxide:

Si(OC2H5)4 → SiO2 + 2 (C2H5)2O
The volatile coproduct is diethyl ether.




Safety


Inhalation of TEOS induces eye and nose irritation, and eye contact with the liquid is irritating. High exposure to TEOS can lead to pulmonary edema, but hazards can be reduced by atmospheric humidity and vapor pressure conditions. The mechanism of irritation is similar to that of tetramethyl orthosilicate.




References






External links


NIST Standard Reference Database 69, June 2005 Release: NIST Chemistry WebBook
CDC – NIOSH Pocket Guide to Chemical Hazards

Kata Kunci Pencarian:

• Tetraethyl orthosilicate
• Orthosilicate
• Colloidal silica
• Tetramethyl orthosilicate
• Triethylsilane
• Ester
• Sol–gel process
• Chemical vapor deposition
• Sandstone
• Silicon