• Source: Thiobenzoic acid
  • Thiobenzoic acid is an organosulfur compound with molecular formula C6H5COSH. It is the parent of aryl thiocarboxylic acids. It is a pale yellow liquid that freezes just below room temperature.
    Thiobenzoic acid is prepared by treatment of benzoyl chloride with potassium hydrosulfide:

    C6H5C(O)Cl + KSH → C6H5C(O)SH + KCl


    Acidity


    With a pKa near 2.5, this acid is almost 100x more acidic than benzoic acid. The conjugate base is thiobenzoate, C6H5COS−.


    See also


    Dithiobenzoic acid


    References

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