• Source: Tris(acetylacetonato)cobalt(III)

Tris(acetylacetonato)cobalt(III) is the coordination complex with the formula Co(C5H7O2)3. Often abbreviated Co(acac)3, it is a green, diamagnetic solid that is soluble in organic solvents, but not in water. Owing to its solubility in organic solvents, tris(acetylacetonato)cobalt(III) is used to produce homogeneous catalysts by reduction.




Structure


The structure of the complex has been confirmed by X-ray crystallography. The three acac− ligands bind in a bidentate fashion to cobalt, defining an octahedral complex. The solid is isomorphous with tris(acetylacetonato)iron(III), tris(acetylacetonato)manganese(III), and tris(acetylacetonato)aluminium. With D3-symmetry, these complexes are chiral and often can be resolved into the individual enantiomers.




Synthesis and reactions


Tris(acetylacetonato)cobalt(III) is prepared by the reaction of cobalt(II) carbonate and acetylacetone in the presence of hydrogen peroxide:

2 CoCO3 + 6 CH3COCH2COCH3 + H2O2 → 2 Co(O2C3Me2H)3 + 2 CO2 + 4 H2O
One distinctive aspect of Co(acac)3 is its susceptibility toward electrophilic aromatic substitution, by which protons on the central carbon are replaced with diverse electrophiles (Me = methyl):

Co(O2C3Me2H)3 + 3 NO2+ → Co(O2C3Me2NO2)3 + 3 H+




References

Kata Kunci Pencarian:

• Tris(acetylacetonato)cobalt(III)
• Tris(acetylacetonato)iron(III)
• Cobalt(II) carbonate
• Metal acetylacetonates
• Chromium(III) acetylacetonate
• Organoiridium chemistry
• Rhodocene