chavicine
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Chavicine is a possibly pungent compound found in black pepper and other species of the genus Piper. It is one of the four geometric isomers of piperine.
In light, especially ultra-violet light, chavicine is formed from its isomer piperine. Its flavor has been reported as flavorless Chavicine will also re-isomerise back to piperine.
See also
Guineesine