- Roentgenium
- Kamus rumus kimia
- Rhenium heptafluoride
- Rhenium
- Heptafluoride
- Rhenium pentachloride
- Fluorine
- Group 7 element
- Rhenium hexafluoride
- Rhenium compounds
- Pentagonal bipyramidal molecular geometry
- Osmium heptafluoride
Rhenium heptafluoride GudangMovies21 Rebahinxxi LK21
Rhenium heptafluoride is the compound with the formula ReF7. It is a yellow low melting solid and is the only thermally stable metal heptafluoride. It has a distorted pentagonal bipyramidal structure similar to IF7, which was confirmed by neutron diffraction at 1.5 K. The structure is non-rigid, as evidenced by electron diffraction studies.
Production, reactions and properties
Rhenium heptafluoride can be prepared from the elements at 400 °C:
2 Re + 7 F2 → 2 ReF7
It also can be produced by the explosion of rhenium metal under sulfur hexafluoride.
It hydrolyzes under a base to form perrhenic acid and hydrogen fluoride:
ReF7 + 4H2O → HReO4 + 7HF
With fluoride donors such as CsF, the ReF−8 anion is formed, which has a square antiprismatic structure. With antimony pentafluoride, SbF5, a fluoride acceptor, the ReF+6 cation is formed.
References
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