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  • Source: Thulium monoselenide
  • Thulium monoselenide is a mixed valence compound of selenium and thulium with the chemical formula TmSe.


    Preparation


    Thulium monoselenide can be prepared by directly reacting thulium and selenium:

    Tm + Se → TmSe


    Properties


    Thulium monoselenide forms reddish-brown cubic crystals, space group Fm3m, unit cell parameters a = 0.5640 nm, Z = 4, and a structure similar to that of sodium chloride.
    The compound melts congruently at 2060 °C, and at 1100 °C and 1730 °C, phase transitions occur in the compound. The Néel temperature of thulium monoselenide is 1.85–2.8 K.


    References

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